469866-37-3Relevant academic research and scientific papers
Palladium-catalyzed asymmetric allylation and complex formation involving P,N-bidentate derivatives of (S)-2-(anilinomethyl)pyrrolidine
Bondarev, O. G.,Gavrilov, K. N.,Tsarev, V. N.,Davankov, V. A.,Lebedev, R. V.,et al.
, p. 521 - 525 (2008/10/08)
P,N-Bidentate (S)-2-(anilinomethyl)pyrrolidine derivatives and their complexes with rhodium(I) and palladium(II) were synthesized. It was demonstrated that these compounds can be used in the Pd-catalyzed asymmetric allylation for the synthesis of chiral methyl 2-phenyl-2-(2-phenyl-o-carboranyl-1)pent-4-enoate.
Pd-catalyzed asymmetric allylation of an o-carborane derivative
Lebedev, R. V.,Moiseev, S. K.,Bondarev, O. G.,Il'in, M. M.,Gavrilov, K. N.,Kalinin, V. N.
, p. 513 - 516 (2007/10/03)
The asymmetric synthesis of methyl 2-phenyl-2-(2-phenyl-ortho-carboran-1-yl)pent-4-enoate was carried out by palladium-catalyzed allylation in the presence of amino phosphites of the type (RO)2P-O-CH2-CHR'-NR''2 as chiral ligands.
