470468-54-3Relevant academic research and scientific papers
Chelation-assisted β-alkylation of α,β-unsaturated ketone using Rh(I) catalyst and dialkyl amine
Jun, Chul-Ho,Moon, Choong Woon,Kim, Young-Min,Lee, Hyuk,Lee, Jun Hee
, p. 4233 - 4236 (2002)
A new Rh(I)-catalyzed β-alkylation of 4-phenyl-3-buten-2-one (1) was developed by utilizing diethylamine (5a) as a chelation-assistant tool. The key feature of this reaction is the vinyl C-H activation driven by amine-assisted cyclometalation to give the
