470669-29-5

Basic information

• Product Name: 9-benzoyl-1-methyl-4-methylene-9-azabicyclo[3.3.1]nonane
• Synonyms: 9-benzoyl-1-methyl-4-methylene-9-azabicyclo[3.3.1]nonane
• CAS NO: 470669-29-5
• Molecular Weight: 255.36
• Mol File: 470669-29-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 9-benzoyl-1-methyl-4-methylene-9-azabicyclo[3.3.1]nonane(CAS DataBase Reference)
• NIST Chemistry Reference: 9-benzoyl-1-methyl-4-methylene-9-azabicyclo[3.3.1]nonane(470669-29-5)
• EPA Substance Registry System: 9-benzoyl-1-methyl-4-methylene-9-azabicyclo[3.3.1]nonane(470669-29-5)

Safety Data

• Hazardous Substances Data: 470669-29-5(Hazardous Substances Data)

Upstream product

• 470669-25-1 (2-iodo-phenyl)-[2-methyl-2-(4-trimethylsilanyl-but-3-ynyl)-piperidin-1-yl]-methanone 
• 470669-23-9 2-(4,4-dibromo-but-3-enyl)-2-methyl-piperidine-1-carboxylic acid tert-butyl ester 
• 470669-18-2 2-(2-ethoxycarbonyl-ethyl)-2-methyl-piperidine-1-carboxylic acid tert-butyl ester 
• 470669-17-1 2-(2-ethoxycarbonyl-vinyl)-2-methyl-piperidine-1-carboxylic acid tert-butyl ester 
• 470669-19-3 2-(3-hydroxy-propyl)-2-methyl-piperidine-1-carboxylic acid tert-butyl ester 
• 470669-31-9 2-methyl-2-(3-oxo-propyl)-piperidine-1-carboxylic acid tert-butyl ester 
• 470668-97-4 2-methyl-piperidine-1,2-dicarboxylic acid 1-tert-butyl ester 2-methyl ester 
• 470669-15-9 tert-butyl 2-(hydroxymethyl)-2-methylpiperidine-1-carboxylate 
• 470669-16-0 2-formyl-2-methyl-piperidine-1-carboxylic acid tert-butyl ester 
• 132910-79-3 (+/-) methyl N-tert-butyloxycarbonyl 2-piperidinecarboxylate 
• 470669-27-3 9-benzoyl-1-methyl-4-(trimethylsilylmethylene)-9-azabicyclo[3.3.1]nonane 

Downstream Products

• 470669-11-5 9-benzoyl-4-(trifluoromethylsulfonyloxy)-1-methyl-9-azabicyclo[3.3.1]non-3-ene 
• 470669-30-8 9-benzoyl-1-methyl-9-azabicyclo[3.3.1]nonan-4-one 

Relevant articles and documents

A new entry to 9-azabicyclo[3.3.1]nonanes using radical translocation/cyclisation reactions of 2-(but-3-ynyl)-1-(o-iodobenzoyl)piperidines

The 2-[4-(trimethylsilyl) but-3-ynyl]piperidines 16a-c, upon treatment with tributyltin hydride in the presence of azoisobutyronitrile in refluxing toluene, gave the 9-azabicyclo[3.3.1]nonanes 17a-c in high yields, respectively. Compound 17c was subjected to desilylation, ozonolysis, and subsequent 1,2-transposition of the resulting carbonyl group to give 9-benzoyl-1-methyl-9-azabicyclo[3.3.1]nonan-3-one, a potential precursor for the synthesis of (±)-euphococcinine.