470671-32-0

Basic information

• Product Name: tert-butyl-dimethyl-(4-phenyl-buta-1,3-diynyl)-silane
• Synonyms: tert-butyl-dimethyl-(4-phenyl-buta-1,3-diynyl)-silane
• CAS NO: 470671-32-0
• Molecular Weight: 240.42
• Mol File: 470671-32-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: tert-butyl-dimethyl-(4-phenyl-buta-1,3-diynyl)-silane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl-dimethyl-(4-phenyl-buta-1,3-diynyl)-silane(470671-32-0)
• EPA Substance Registry System: tert-butyl-dimethyl-(4-phenyl-buta-1,3-diynyl)-silane(470671-32-0)

Safety Data

• Hazardous Substances Data: 470671-32-0(Hazardous Substances Data)

Upstream product

• 86318-61-8 (tert-butyldimethylsilyl)acetylene 
• 536-74-3 phenylacetylene 
• 107474-01-1 (tert-butyldimethylsilyl)(trimethylsilyl)acetylene 
• 1377860-93-9 1-[2-(tert-butyldimethylsilyl)ethynyl]-1,2-benziodoxol-3(1H)-one 
• 932-87-6 1-Bromo-2-phenylacetylene 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 20264-56-6 1,6-diphenyl-1,3,5-hexatriyne 

Relevant articles and documents

Bulky trialkylsilyl acetylenes in the Cadiot-Chodkiewicz cross-coupling reaction

Bulky trialkylsilyl-protected alkynes such as triethylsilyl (TES), tert-butyldimethylsilyl (TBS), and tri-isopropylsilyl (TIPS) acetylenes underwent the Cadiot-Chodkiewicz cross-coupling reaction with different bromoalkynes to form a variety of synthetically useful unsymmetrical diynes in good yields. The diyne alcohol 10 was transformed regio- and stereoselectively into enynes by hydrotelluration, carbometalation, and reduction reactions.

Nickel-catalyzed oxidative coupling reactions of two different terminal alkynes using O2 as the oxidant at room temperature: Facile syntheses of unsymmetric 1,3-diynes

(Formula Presented) Two different terminal alkynes now can be coupled together in the presence of NiCl2-6H2O/Cul by using an excess of one of the terminal alkyne substrates. The new method employed 20 mol % TMEDA as the ligand and environmentally benign O2 or air as the oxidant. It is the first example using Ni-salt as catalyst by employing air or O2 as oxidant, which led to efficient heterocoupling of two different alkynes.