4708-20-7Relevant academic research and scientific papers
REACTION OF SINGLET OXYGEN WITH AZINES: IMPLICATIONS FOR DIOXIRANE INTERMEDIATE
Ando, Wataru,Sato, Rikiya,Sonobe, Hideki,Akasaka, Takeshi
, p. 853 - 856 (1984)
Photooxygenation of tricyclodecanone azine (adamantanone azine) afforded, in addition to adamantanone, 4-oxohomoadamantan-5-one derived from a dioxirane intermediate via a non-radical pathway.
SINGLET OXYGEN AND TRIAZOLINEDIONE ADDITION TO AZINES
Sato, Rikiya,Sonobe, Hideki,Akasaka, Takeshi,Ando, Wataru
, p. 5273 - 5280 (2007/10/02)
Photooxygenation of azines, i.e., adamantanone azine (1) and benzonorborn-7-one azine (4), afforded in addition to the corresponding ketones, lactones derived from a carbonyl oxide intermediate via an electron transfer pathway.On the other hand, 4-substitued-1,2,4-triazoline-3,5-diones (TAD) react with azine 1 to give a 1,3-dipole, an azomethinimine intermediate as nitrogen analogue of a carbonyl oxide, which afforded the -cycloadducts in treatment with dipolarophiles.The mechanistic implications are discussed.
