471270-17-4

Upstream product

• 301823-99-4 C₃₅H₄₄O₆Si 
• 471269-87-1 (1R,2S,4R,5S)-5-{(tert-butyldiphenylsilyloxy)-3,3-dimethyl-1-[(2R*)-tetrahydropyran-2-yloxymethyl]-7-oxabicyclo[2.2.1]heptane-2-yl}methanol 
• 471269-82-6 (1R,2S,4R,5S)-tert-butyl{6,6-dimethyl-4-[(2R*)-tetrahydropyran-2-yloxymethyl]-5-vinyl-7-oxabicyclo[2.2.1]heptan-2-yloxy}diphenylsilane 
• 471269-88-2 (1R,2S,4R,5S)-5-(tert-butyldiphenylsilyloxy)-3,3-dimethyl-1-[(2R*)-tetrahydropyran-2-yloxymethyl]-7-oxabicyclo[2.2.1]heptane-2-carbaldehyde 
• 471269-86-0 (1R,2S,4R,5S)-5-hydroxy-3,3-dimethyl-1-[(2R*)-tetrahydropyran-2-yloxymethyl]-7-oxabicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester 
• 301823-96-1 (1R,2S,4S)-3,3-dimethyl-1-[(2R*)-tetrahydropyran-2-yloxymethyl]-7-oxabicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester 
• 470690-19-8 (1R,2S,4S)-1-hydroxymethyl-3,3-dimethyl-7-oxabicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester 
• 301823-95-0 (+)-(1R,5S,7S)-6,6-dimethyl-10-oxa-3-azatricyclo[5.2.1.o^1,5]dec-8-en-4-one 
• 77704-39-3 (-)-(1R,5S,7S)-3-[(1R)-2-hydroxy-1-phenylethyl]-6,6-dimethyl-10-oxa-3-azatricyclo[5.2.1.0^1,5]dec-8-en-4-one 
• 77704-70-2 (-)-(R)-N-<(Furan-2-yl)methyl>-N-(2-hyydroxy-1-phenylethyl)-3-methylbut-2-enamid 
• 301823-98-3 (+)-(S)-acetic acid [2-(tert-butyldimethylsilyloxymethyl)cyclohex-1-enyl][(1R,2S,4R,5S)-5-(tert-butyldiphenylsilyloxy)-3,3-dimethyl-2-vinyl-7-oxabicyclo[2.2.1]heptan-1-yl]methyl ester 
• 471270-02-7 (+)-(S)-[2-(tert-butyldimethylsilyloxymethyl)cyclohex-1-enyl][(1R,2S,4R,5S)-5-(tert-butyldiphenylsilyloxy)-3,3-dimethyl-2-vinyl-7-oxabicyclo[2.2.1]heptan-1-yl]methanol 
• 471270-03-8 (S)-acetic acid [(1R,2S,4R,5S)-5-(tert-butyldiphenylsilyloxy)-3,3-dimethyl-2-vinyl-7-oxabicyclo[2.2.1]heptan-1-yl](2-hydroxymethylcyclohex-1-enyl)methyl ester 
• 301823-92-7 (-)-(S)-acetic acid [(1R,2S,4R,5S)-5-(tert-butyldiphenylsilyloxy)-3,3-dimethyl-2-vinyl-7-oxabicyclo[2.2.1]heptan-1-yl](2-vinylcyclohex-1-enyl)methyl ester 

Downstream Products

• 301824-00-0 C₃₆H₄₄O₆Si 

Relevant academic research and scientific papers

Studies towards the total synthesis of solanoeclepin A: Synthesis and potato cyst nematode hatching activity of analogues containing the tetracyclic left-hand substructure

In our studies towards the total synthesis of solanoeclepin A, a natural hatching agent of potato cyst nematodes, three analogues containing the tetracyclic left-handed substructure have been synthesised. First, the synthesis of the parent tetracycle 2 in

Enantioselectve synthesis of the tetracyclic left-hand substructure of solanoeclepin A

The synthesis of the enantiopure left-hand substructure of solanoeclepin A is described. Key steps include a chromium-mediated coupling of an oxabicyclic aldehyde with a β-ketoester-derived enol triflate to give a lactone, and a ring-closing metathesis reaction to form the seven-membered ring.