4714-35-6Relevant academic research and scientific papers
THIOCYANATO-, BROMO-, AND CHLOROARYLATION OF TRICHLOROETHYLENE
Grishchuk, B. D.,Kudrik, E. Ya.,Gorbovoi, P. M.,Garmider, V. L.,Ganushchak, N. I.
, p. 1164 - 1166 (2007/10/02)
By reactions of arenediazonium salts with trichloroethylene in aqueous acetone in the presence of alkali metal thiocyanates, bromides, or chlorides, catalyzed by Cu(II) or Fe(II) salts, we synthesized 1-thiocyanato(bromo, chloro)-1,2,2-trichloro-2-arylethanes.These were treated with alcoholic potassium hydroxide to give α,β,β-trichlorostyrenes.Trichloroethylene is less reactive in the anionarylation than vinylidene and vinyl chlorides.
