471913-24-3

Upstream product

• 471913-18-5 acetic acid {2-(tert-butyl-dimethyl-silanyloxymethyl)-4-[2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropylmethyl]-cyclohex-1-enyl}-[5-(tert-butyl-diphenyl-silanyloxy)-3,3-dimethyl-2-vinyl-7-oxa-bicyclo[2.2.1]hept-1-yl]-methyl ester 
• 471913-17-4 {2-(tert-butyl-dimethyl-silanyloxymethyl)-4-[2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropylmethyl]-cyclohex-1-enyl}-[5-(tert-butyl-diphenyl-silanyloxy)-3,3-dimethyl-2-vinyl-7-oxa-bicyclo[2.2.1]hept-1-yl]-methanol 
• 471913-19-6 Acetic acid (S)-[(1R,2S,4R,5S)-5-(tert-butyl-diphenyl-silanyloxy)-3,3-dimethyl-2-vinyl-7-oxa-bicyclo[2.2.1]hept-1-yl]-{4-[2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropylmethyl]-2-hydroxymethyl-cyclohex-1-enyl}-methyl ester 
• 471913-21-0 Acetic acid (S)-[(1R,2S,4R,5S)-5-(tert-butyl-diphenyl-silanyloxy)-3,3-dimethyl-2-vinyl-7-oxa-bicyclo[2.2.1]hept-1-yl]-{4-[2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropylmethyl]-2-vinyl-cyclohex-1-enyl}-methyl ester 
• 471913-20-9 Acetic acid (S)-[(1R,2S,4R,5S)-5-(tert-butyl-diphenyl-silanyloxy)-3,3-dimethyl-2-vinyl-7-oxa-bicyclo[2.2.1]hept-1-yl]-{4-[2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropylmethyl]-2-formyl-cyclohex-1-enyl}-methyl ester 
• 471913-16-3 (S)-[(1R,2S,4R,5S)-5-(tert-Butyl-diphenyl-silanyloxy)-3,3-dimethyl-2-vinyl-7-oxa-bicyclo[2.2.1]hept-1-yl]-{4-[2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropylmethyl]-2-hydroxymethyl-cyclohex-1-enyl}-methanol 
• 471913-22-1 C₅₆H₇₀O₅Si₂ 
• 471913-15-2 3-[5-(tert-butyl-diphenyl-silanyloxy)-3,3-dimethyl-2-vinyl-7-oxa-bicyclo[2.2.1]hept-1-yl]-6-[2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropylmethyl]-4,5,6,7-tetrahydro-3H-isobenzofuran-1-one 
• 301823-94-9 (+)-(1R,2S,4R,5S)-5-(tert-butyldiphenylsilyloxy)-3,3-dimethyl-2-vinyl-7-oxabicyclo[2.2.1]heptancarboxaldehyde 
• 471269-86-0 (1R,2S,4R,5S)-5-hydroxy-3,3-dimethyl-1-[(2R*)-tetrahydropyran-2-yloxymethyl]-7-oxabicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester 
• 301823-96-1 (1R,2S,4S)-3,3-dimethyl-1-[(2R*)-tetrahydropyran-2-yloxymethyl]-7-oxabicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester 
• 470690-19-8 (1R,2S,4S)-1-hydroxymethyl-3,3-dimethyl-7-oxabicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester 
• 471269-87-1 (1R,2S,4R,5S)-5-{(tert-butyldiphenylsilyloxy)-3,3-dimethyl-1-[(2R*)-tetrahydropyran-2-yloxymethyl]-7-oxabicyclo[2.2.1]heptane-2-yl}methanol 
• 471269-82-6 (1R,2S,4R,5S)-tert-butyl{6,6-dimethyl-4-[(2R*)-tetrahydropyran-2-yloxymethyl]-5-vinyl-7-oxabicyclo[2.2.1]heptan-2-yloxy}diphenylsilane 

Downstream Products

• 471913-26-5 C₅₇H₇₀O₇Si₂ 
• 471913-25-4 C₅₆H₆₈O₇Si₂ 

Relevant academic research and scientific papers

Studies towards the total synthesis of solanoeclepin A: Synthesis and potato cyst nematode hatching activity of analogues containing the tetracyclic left-hand substructure

In our studies towards the total synthesis of solanoeclepin A, a natural hatching agent of potato cyst nematodes, three analogues containing the tetracyclic left-handed substructure have been synthesised. First, the synthesis of the parent tetracycle 2 in