471930-06-0Relevant articles and documents
(π-Allyl)palladium complexes bearing diphosphinidenecyclobutene ligands (DPCB): Highly active catalysts for direct conversion of allylic alcohols
Ozawa, Fumiyuki,Okamoto, Hideyuki,Kawagishi, Seiji,Yamamoto, Shogo,Minami, Tatsuya,Yoshifuji, Masaaki
, p. 10968 - 10969 (2002)
The (π-allyl)palladium complex bearing an sp2-hybridized phosphorus ligand (DPCB-OMe: 1,2-bis(4-methoxyphenyl)-3,4-bis[(2,4,6-tri-tert-butylphenyl)phosphinidene]cyclobutene) efficiently catalyzes direct conversion of allylic alcohols in the absence of activating agents of alcohols such as Lewis acids. N-Allylation of aniline proceeds at room temperature to afford monoallylated anilines in 90-97% yields. C-Allylation of active methylene compounds is also successful at 50 °C using a catalytic amount of pyridine as a base, giving monoallylation products in 85-95% yields. The catalytic mechanism involving hydrido- and (π-allyl)palladium intermediates has been proposed on the basis of stoichiometric examinations using model compounds of presumed intermediates. Copyright
