473-00-7Relevant academic research and scientific papers
PRODUCTS FROM SOLVOLYSIS OF 2-(2-TOSYLOXYETHYL)-6,6-DIMETHYLBICYCLOHEPT-2-ENE
Vyglazov, O. G.,Urbanovich, T. R.,Manukov, E. N.,Chuiko, V. A.,Udarov, B. G.
, p. 1896 - 1900 (2007/10/02)
The solvolysis of 2-(2-tosyloxyethyl)-6,6-dimethylbicyclohept-2-ene takes place with retention of the gem-dimethylcyclobutane ring of the substrate and is accompanied by simultaneous opening of the additional three-or four-membered ring in the reaction product.
Rearrangements of Pinane Derivatives. Part 91. 8,8-Dimethyltricyclo-2,5>nonan-2β-ol, a Tricyclic Pinane Derivative
Giddings, Rodney M.,Jones-Parry, Richard,Owen, Rawson,Whittaker, David
, p. 1525 - 1528 (2007/10/02)
Acetolysis of the toluene-p-sulphonate ester of 2-(2-hydroxyethyl)-6,6-dimethylbicyclohept-2-ene (nopol) (1; R = OH) gave a good yield of the acetate of the previously unknown tricyclic pinane derivative 8,8-dimethyltrycyclo2,5>n
