4730-93-2Relevant academic research and scientific papers
π4s+ π2s Cycloaddition of spiro[4,n]cyclic 1,3-dienes with quinones in homogeneous and aqueous micellar media: Synthesis of novel polycyclic cage diones
Singh, Vishwakarma,Raju, Bhupathiraju N. S.
, p. 303 - 311 (2007/10/03)
Synthesis of novel cage polycyclic diones 22-27 via micellar Diels-Alder reaction of spirocyclopentadienes 7-9 with various quinones followed by intramolecular photocycloaddition has been reported. A simple phase transfer catalyzed preparation of the requisite dienes 7-9 has also been described. A remarkable micellar catalysis on the Diels-Alder reaction has been observed.
