4733-73-7

Usage

Physical state

Colorless liquid

Odor

Strong amine odor

Uses

+ Building block in pharmaceuticals, agrochemicals, and electronic materials
+ Polymerization regulator in polyurethane production
+ Corrosion inhibitor in water treatment
+ Potential applications in organic synthesis and as a solvent in chemical processes

Toxicity

Toxic if ingested

Hazards

Can cause skin and eye irritation

Safety

Handle with caution and follow proper safety protocols when using.

InChI:InChI=1/C8H17N/c1-7-5-4-6-8(2)9(7)3/h7-8H,4-6H2,1-3H3

Upstream product

• 112269-97-3 2,2,6-trimethyl-2,3,4,5-tetrahydropyridine 

Relevant academic research and scientific papers

Asymmetric synthesis of α-alkylated aldehydes using terminal epoxide-derived chiral enamines

(Chemical Equation Presented) Effective discrimination: Efficient lithium amide-induced terminal epoxide-enamine transformation provides the first enamines capable of generating α-alkylated aldehydes with high asymmetric induction by intermolecular nucleophilic substitution (see scheme).

MECHANISMS OF FREE-RADICAL REACTIONS. XXV. REACTIVITY OF N-CHLORO-2,2,6,6-TETRAMETHYLPIPERIDINE IN FREE-RADICAL CHLORINATION OF ALIPHATIC COMPOUNDS

The chlorination of 2,3-dimethylbutane and cyclohexane by N-chloropiperidine and N-chloro-2,2,6,6-tetramethylpiperidine was studied.The rate of abstraction of the hydrogen atom from various positions is determined mainly by the dissociation energies of the respective C-H bonds.The higher reactivity of the R2CH2 group compared with R3CH for the last reagent is due to the significant sensitivity of the radical to steric factors.In the absence of highly reactive substrates N-chloro-2,2,6,6-tetramethylpiperidine dissociates through β-fragmentation of the radical-cation.