473467-89-9Relevant academic research and scientific papers
The [Re(CO)6]+ cation as a ligand-transfer reagent with ferrocene derivatives
Top, Siden,Masi, Stephane,Jaouen, Gerard
, p. 1848 - 1853 (2002)
The [Re(CO)6]+ cation is a stable compound, soluble in aqueous media. We show that it can be used as a reagent in the synthesis of tricarbonyl(cyclopentadienyl)rhenium complexes. [Re(CO)6]+ reacts with ferrocene derivatives, particularly acetylferrocene, in DMSO, DMF or a water/DMSO (1:1) mixture at 160 °C to give tricarbonyl(cyclopentadienyl)rhenium derivatives with high yields. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.
