473914-75-9Relevant academic research and scientific papers
N,3,4-Trisubstituted pyrrolidines by electron transfer-induced oxidative cyclizations of N-allylic β-amino ester enolates
Jahn, Ullrich,Kafka, Franti?ek,Pohl, Radek,Jones, Peter G.
experimental part, p. 10917 - 10929 (2010/02/27)
Oxidative radical cyclizations starting from easily accessible N-allylic β-alanine esters are reported. Deprotonation generates the corresponding enolates, which are transformed efficiently into α-ester radicals by single electron transfer mediated by fer
Facile synthesis of substituted 2,3,4,7-tetrahydro-1H-azepines via ring-closing metathesis
Brass, Sascha,Gerber, Hans-Dieter,D?rr, Stefanie,Diederich, Wibke E.
, p. 1777 - 1786 (2007/10/03)
A highly efficient synthesis based on inexpensive and readily available starting material towards the pharmacologically interesting class of substituted 2,3,4,7-tetrahydro-1H-azepines via a ring-closing metathesis (RCM) approach employing Grubbs catalysts
