473935-18-1

Upstream product

• 28447-15-6 trans-3-(3-pyridyl)acrolein 
• 1449-46-3 benzyltriphenylphosphonium bromide 
• 338741-53-0 (1Z,3E)-1-(3-pyridyl)-4-(phenyl)buta-1,3-diene 
• 52378-67-3 (E,E)-1-(3-pyridyl)-4-(phenyl)buta-1,3-diene 

Downstream Products

• 338741-53-0 (1Z,3E)-1-(3-pyridyl)-4-(phenyl)buta-1,3-diene 
• 52378-67-3 (E,E)-1-(3-pyridyl)-4-(phenyl)buta-1,3-diene 

Relevant academic research and scientific papers

Photoisomerization mechanisms and photoselectivity of the stereoisomers of 1-(pyrid-n-yl),4-phenylbuta-1,3-diene

The positional isomers of 1-(pyrid-n-yl),4-phenylbuta-1,3-diene (n = 2, 3 and 4) have been synthesized and characterized by spectrometric techniques. All the four expected stereoisomers (EE, EZ, ZE and ZZ) were prepared for n = 2 while only three and two geometrical isomers were obtained for the positional isomers with n = 3 and 4, respectively. Their excited state properties were investigated by stationary and pulsed fluorimetric techniques and by laser flash photolysis. This paper describes the photochemical behaviour under direct and triplet sensitized excitation. The selective formation of photoproducts and the role of diabatic/adiabatic mechanisms are reported and compared with the results on the direct photoisomerization of the EE and ZE isomers in the singlet manifold described in a previous paper (G. Bartocci, G. Galiazzo, U. Mazzucato and A. Spalletti, Phys. Chem. Chem. Phys., 2001, 3, 379-386).