474262-71-0Relevant academic research and scientific papers
Lewis base-catalysed Mukaiyama-aldol reaction of trimethylsilyl enolates with aldehydes
Zhang, Xingxian,Shi, Junchen,Hu, Shenghui
experimental part, p. 263 - 265 (2010/10/04)
An efficient Mukaiyama-type aldol reaction of three typical silyl enolates, such as 1-(trimethylsiloxy)-1-methoxy-2-methyl-2-propene, 1-phenyl-1- trimethylsilyloxyethene and 1, 2-bis(trimethylsiloxy)cyclobutene, with aryl aldehydes and a,β-unsaturated ald
Chemoselective aldol reaction of silyl enolates catalyzed by Mgl2 etherate
Li, Wei-Dong Z.,Zhang, Xing-Xian
, p. 3485 - 3488 (2007/10/03)
(matrix presented) Mukaiyama-type aldol coupling of typical silyl enolates 2-4 with aryl or vinyl aldehydes and acetals was realized in the presence of 1-5 mol % of MgI2 etherate (1) in a mild, efficient, and highly chemoselective manner. Iodid
