474382-30-4Relevant academic research and scientific papers
A tetranuclear heterobimetallic square formed from the cooperative ligand binding properties of square planar and tetrahedral metal centers
Gianneschi, Nathan C.,Mirkin, Chad A.,Zakharov, Lev N.,Rheingold, Arnold L.
, p. 5326 - 5328 (2002)
Reaction of Rh(I) and ZN(II) metal centers with a ligand containing salicylaldiminato and thioether-phosphine moieties resulted in the formation of a tetranuclear heterobimetallic molecular square. The directionality required to form these structures is imparted by both the tetrahedral and square planar metal centers acting in concert with one another.
