474452-91-0Relevant academic research and scientific papers
Unexpected cyclization of tritylamines promoted by copper salt through c-h and c-n bond cleavages to produce acridine derivatives
Morioka, Ryosuke,Hirano, Koji,Satoh, Tetsuya,Miura, Masahiro
, p. 12720 - 12724 (2014)
Herein, we demonstrate that tritylamines undergo an unprecedented copper-mediated cyclization involving the cleavages of two C-H bonds and one C-N bond to give 9-arylacridine derivatives. This kind of acridines is of interest due to their biological properties and their unique optical and electro- and photochemical properties. Some of obtained acridine derivatives exhibit intense fluorescence in the solid state.
