474458-61-2

Usage

Uses

Used in Materials Science:
1-ethynyl-4-((4-(phenylethynyl)phenyl)ethynyl)benzene is used as a model compound for studying the electronic and optical properties of PAHs, contributing to the development of advanced materials with tailored properties for various applications.
Used in Organic Electronics:
T4 is used as a component in the research and development of organic electronic devices, such as organic light-emitting diodes (OLEDs) and organic photovoltaics (OPVs), due to its unique structure and properties that can enhance device performance.
Used in Chemical Research:
1-ethynyl-4-((4-(phenylethynyl)phenyl)ethynyl)benzene is used as a subject of study in the field of organic chemistry and materials science, where its complex molecular structure and potential applications are explored to advance scientific understanding and innovation.

Upstream product

• 176977-34-7 ((4-((trimethylsilyl)ethynyl)phenyl)-ethynyl)triisopropylsilane 
• 175345-90-1 1-((triisopropylsilyl)ethynyl)-4-ethynylbenzene 
• 134856-58-9 1-iodo-4-(trimethylsilylethynyl)benzene 
• 624-38-4 para-diiodobenzene 

Downstream Products

• 695228-01-4 [Ru(PhC(CC₆H₄)2CC)(2,2':6',2''-terpyridine)(2,2'-bipyridine)](ClO₄) 
• 886972-14-1 trans-PtCl(C₂((C₆H₄)C₂)2(C₆H₅))(PBu₃)2 
• 932029-40-8 trans-Pt(II)(tributylphosphine)2(CCC₆H₅)(CCC₆H₄CCC₆H₄CCC₆H₅) 
• 1231725-98-6 [4,6-diphenyl-2,2'-bipyridyl]Pt(CCC₆H₄CCC₆H₄CCC₆H₅) 
• 97765-42-9 1,4-bis(4-(phenylethynyl)phenylethynyl)benzene 

Relevant academic research and scientific papers

Geometrically homogenous series of covalently linked zinc/free-base porphyrin dimers of varying length; design, synthesis and characterization

Singlet excitation energy transfer, SEET, can be mediated by a bridge, connecting an energy donor and acceptor, via a superexchange mechanism. The mediation efficiency depends on the energy difference between the first excited states of the donor and the bridge, ΔEDB, as well as the donor-acceptor distance, RDA. We have previously constructed a series of donor-bridge-acceptor, D-B-A, systems that allowed us to study how SEET depends on ΔEDB. To expand this study into a second dimension, the distance dependence, a new series of D-B-A systems were constructed. This series was based on the same zinc/free-base porphyrin couple as the donor-acceptor pair in the previous series. Their relative orientation was also retained. In contrast to our first series, the bridges in the latter were of varying length. The bridges were oligo(phenyleneethynylene)phenylene (OPE) structures and the length was systematically changed by increasing the number of phenyleneethynylene units from 1 to 4. To obtain high quality samples, the D-B-A systems were assembled by a building block approach where the zinc and free-base porphyrins were introduced separately using Heck alkynylations. The performance of the OPE structure as a mediator and scaffold is discussed in terms of singlet excited state energies and flexibility. For the first time, when combining the topical D-B-A systems with our previous subset, a homogeneous series of D-B-A systems has been synthesized that allows for studies of both the distance dependence and the energy difference dependence of SEET. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.