474511-65-4Relevant academic research and scientific papers
Synthesis, characterisation and reactivity of a novel iridaphosphirene complex, [Ir{=C(But)P(Cy)}(CO)(PPH3)2], Cy = cyclohexyl
Brym, Markus,Jones, Cameron,Richards, Anne F.
, p. 2800 - 2801 (2002)
The reaction of the phosphavinyl Grignard reagent,[CyP=C(But)MgCl(O Et2)], Cy = cyclohexyl, with Vaska's compound affords the first example of an iridaphosphirene complex, [Ir{=C(But)P(Cy)}(CO)(PPh3)2], which has been crystallographically characterised and its reaction with CO examined.
