474654-47-2

Basic information

• Product Name: rhenium benzene ion
• CAS NO: 474654-47-2
• Molecular Weight: 264.321
• Mol File: 474654-47-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: rhenium benzene ion(CAS DataBase Reference)
• NIST Chemistry Reference: rhenium benzene ion(474654-47-2)
• EPA Substance Registry System: rhenium benzene ion(474654-47-2)

Safety Data

• Hazardous Substances Data: 474654-47-2(Hazardous Substances Data)

Upstream product

• 74-98-6 propane 

Relevant articles and documents

Reactions of Re+, Re2+, and ReOx+ ions with small hydrocarbon molecules in the gas phase

Reactions of the Re+ and Re2+ ions and the ReOx+ (x = 1-3) oxygen-containing ions with methane, propane, propylene, and cyclopropane were studied by ion cyclotron resonance. The formation of several organometallic ions, Re(C3H6)+, Re(C3H4)+, Re2(C3H6)+, and Re2(C3H4)+, including rhenium metallocarbene ReCH2+ and oxometallocarbenes ReOx-1 CH2 (x = 2, 3), was observed. The upper and lower bounds for bond energies in these complexes were determined, namely, 111 > D°(Re+-CH2) > 88.4, D°(Re+-C3H6) > 69, D°(Re2+-C3H6) > 69, D°(Re+-C3H4) > 70.5, D°(Re2+-C3H4) > 70.5, D°(ReO+-CH2) > 110, and D°(ReO2+-CH2) > 118 kcal/mol.