474669-87-9

Upstream product

• 220886-58-8 (3aS,8aR)-2-methyl-8,8a-dihydro-3aH-indeno[1,2-d]oxazole 
• 7480-35-5 (1S,2R)-1-amino-2-indanol 
• 474669-86-8 (3aS,8aR)-3a,8a-dihydro-2-(p-toluenesulfinylmethyl)-8H-indeno[1,2-d]-1,3-oxazole 
• 74-88-4 methyl iodide 

Relevant academic research and scientific papers

Lewis acid-catalyzed asymmetric diels-alder reactions using chiral sulfoxide ligands: chiral 2-(arylsulfinylmethyl)-1,3-oxazoline derivatives.

New chiral sulfoxide-1,3-oxazoline ligands have been developed as chiral ligands for Lewis acid-catalyzed asymmetric Diels-Alder reactions. The use of chiral sulfinyl 1,3-oxazoline ligands in copper(II)-catalyzed asymmetric Diels-Alder reactions provided an endo cycloadduct as a major product with moderate enantioselectivity. A rationale is proposed for the mechanism of the asymmetric induction.