474832-83-2Relevant academic research and scientific papers
Study of the reactivity of 2-acetyl-, 2-cyano-, 2-formyl-, and 2-vinylphenyl palladium(II) complexes. Mono- and triinsertion of an isocyanide into the Pd-C bond. A 2-cyanophenyl palladium complex as a ligand
Vicente, José,Abad, José-Antonio,Martínez-Viviente, Eloísa,Jones, Peter G.
, p. 4454 - 4467 (2008/10/08)
A study of the reactivity of the [Pd(C6H4X-2)Br(bpy)] (bpy = 2,2′-bipyridine; X = C(O)Me, CN, CHO, CH=CH2) complexes was presented. The 2-R-arylpalladium(II) complexes reacted with XyNC (Xy = 2,6-dimethylphenyl) to give different mono- and triinserted complexes depending upon the nature of X, the other ligands and the reaction conditions. The crystal structures of the prepared complexes were also reported.
