4749-27-3

Basic information

• Product Name: 3,3,3-Trichloro-2-methyl-1-propene
• Synonyms: 3,3,3-Trichloro-2-methyl-1-propene
• CAS NO: 4749-27-3
• Molecular Formula: C₄H₅Cl₃
• Molecular Weight: 159.4415
• Mol File: 4749-27-3.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 147.67°C (estimate)
• Flash Point: 61.7°C
• Appearance: /
• Density: 1.2930
• Vapor Pressure: 6.82mmHg at 25°C
• Refractive Index: 1.4770
• CAS DataBase Reference: 3,3,3-Trichloro-2-methyl-1-propene(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3,3-Trichloro-2-methyl-1-propene(4749-27-3)
• EPA Substance Registry System: 3,3,3-Trichloro-2-methyl-1-propene(4749-27-3)

Safety Data

• Hazardous Substances Data: 4749-27-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C4H5Cl3/c1-3(2)4(5,6)7/h1H2,2H3

Upstream product

• 7719-09-7 thionyl chloride 
• 57-15-8 1,1,1-trichloro-2-methyl-2-propanol 
• 121-69-7 N,N-dimethyl-aniline 
• 91-22-5 quinoline 
• 597-37-5 1,1,1-trichloro-2-methylpropan-2-yl acetate 

Downstream Products

• 31702-33-7 1,1,3-trichloro-2-methylprop-1-ene 
• 39109-72-3 1,1-dichloro-3-(4-chloro-phenyl)-2-methyl-propene 
• 4749-31-9 1,1,1,2,3-pentachloro-2-methyl-propane 
• 106272-11-1 N_.N-Bis-(3.3-dichlor-2-methylallyl)-anilin 
• 99071-02-0 N-(3,3-dichloro-2-methyl-allyl)-aniline 
• 117884-07-8 4-(3,3-dichloro-2-methyl-allyl)-anisole 
• 103852-62-6 2-(3,3-dichloro-2-methyl-allyl)-4-methyl-phenol 

Relevant articles and documents

Correlation of Alkyl and Polar Substituents at the Alcoholic Side of Tertiary Acetates with the Rate of Pyrolyses in the Gas Phase

The rate coefficients for the gas-phase pyrolysis of several tertiary acetates have been measured in a static system over the temperature range of 220-340 deg C and pressure range of 40-186 torr.In seasoned vessels the reactions are homogeneous, follow a first-order rate law, and are unimolecular.The temperature dependence of the rate coefficients is given by the following Arrhenius equations: for 3,3,3-trichloro-2-methyl-2-propyl acetate, log k1 (s-1) = (13.86 +/- 0.35) - (188.8 +/- 3.8) kJ mol-1 (2.303 RT)-1; for methyl α-acetoxyisobutyrate, log k1 (s-1) = (12.42 +/- 0.28) - (174.6 +/- 3.2) kJ mol-1 (2.303 RT)-1; for 2-methyl-2-hexyl acetate, log k1 (s-1) = (13.35 +/- 0.33) - (166.1 +/- 3.4) kJ mol-1 (2.303 RT)-1; for 2,4-dimethyl-2-pentyl acetate, log k1 (s-1) = (12.42 +/- 0.19) - (154.1 +/- 1.9) kJ mol-1 (2.303 RT)-1; for 2-methyl-2-acetoxy-4-phenylbutane, log k1 (s-1) = (11.97 +/- 0.55) - (151.5 +/-5.6) kJ mol-1 (2.303 RT)-1.The effectof substituents in the gas-phase elimination of 2-substituted 2-propyl acetates may be either electronic or steric in nature.The linear correlations for electron-releasing groups and for electron-withdrawing groups are presented and discussed.The results of the present work together with those reported in the literature lead to the establishment of a possible generalization on the influence of substituents at the alcohols side of primary, secondary, and tertiary acetates pyrolyses in the gas phase.