474941-36-1

Basic information

• Product Name: [(C₆H₅)C(CH₃O)(C₆F₅)PdBr]2
• CAS NO: 474941-36-1
• Molecular Weight: 947.066
• Mol File: 474941-36-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(C₆H₅)C(CH₃O)(C₆F₅)PdBr]2(CAS DataBase Reference)
• NIST Chemistry Reference: [(C₆H₅)C(CH₃O)(C₆F₅)PdBr]2(474941-36-1)
• EPA Substance Registry System: [(C₆H₅)C(CH₃O)(C₆F₅)PdBr]2(474941-36-1)

Safety Data

• Hazardous Substances Data: 474941-36-1(Hazardous Substances Data)

Upstream product

• 125475-73-2 bis(acetonitrile)bromo(pentafluorophenyl)palladium(II) 
• 37823-96-4 pentacarbonyl(methoxyphenylmethylene)tungsten⁽⁰⁾ 

Relevant articles and documents

Observation of the direct products of migratory insertion in aryl palladium carbene complexes and their subsequent hydrolysis

The interaction of an electrophilic carbene carbon atom with the π-electron density of an aryl group favors an intramolecular migratory insertion reaction (see scheme; Pf = C6F5). This reaction gives alkyl compounds (2 or 3) which ca