474960-25-3Relevant academic research and scientific papers
A mild deprotection strategy for allyl-protecting groups and its implications in sequence specific dendrimer synthesis
Vutukuri, Dharma Rao,Bharathi, Pandi,Yu, Zhouying,Rajasekaran, Karthik,Tran, My-Huyen,Thayumanavan
, p. 1146 - 1149 (2007/10/03)
A mild deprotection strategy for allyl ethers under basic conditions in the presence of a palladium catalyst is described. Under these conditions, aryl allyl ethers can be cleaved selectively in the presence of alkyl allyl ethers. These conditions are also effective in the deprotection of allyloxycarbonyl groups. The utility of the current methodology in sequence specific dendrimer synthesis is demonstrated.
Functional group diversity in dendrimers
Sivanandan, Kulandaivelu,Vutukuri, Dharmarao,Thayumanavan
, p. 3751 - 3753 (2007/10/03)
(graph presented) A methodology for synthesizing dendrons with different peripheral functionalities is described. The benzyl ether-based dendrons reported here were synthesized using allyl and methoxymethyl ether-based protection-deprotection strategies.
