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4,8,8-trimethyldecahydro-1,4-methanoazulen-9-ol is a complex organic compound with the molecular formula C14H26O. It is a derivative of the azulenol family, characterized by its unique cyclic structure and the presence of three methyl groups at positions 4, 8, and 8, as well as a hydroxyl group at position 9. 4,8,8-trimethyldecahydro-1,4-methanoazulen-9-ol is known for its potential applications in the fragrance and flavor industries due to its distinct aroma and taste properties. It is synthesized through various chemical reactions and can be found in trace amounts in natural sources such as essential oils. The compound's structure and properties make it an interesting subject for research in organic chemistry and potential applications in various industries.

475-23-0

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475-23-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 475-23-0 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 4,7 and 5 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 475-23:
(5*4)+(4*7)+(3*5)+(2*2)+(1*3)=70
70 % 10 = 0
So 475-23-0 is a valid CAS Registry Number.

475-23-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 4,8,8-trimethyldecahydro-1,4-methanoazulen-9-ol

1.2 Other means of identification

Product number -
Other names Longicamphenilol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:475-23-0 SDS

475-23-0Downstream Products

475-23-0Relevant academic research and scientific papers

Structure and Odor, VI. - Preparation and Reactions of Longicamphenilone

Weyerstahl,Peter,Krohn,Kerstin

, p. 1125 - 1128 (2007/10/02)

Longicamphenilone (2) can readily be prepared by phase-transfer-catalysed potassium permanganate oxidation of longifolene (1).The ketone 2 is a convenient starting material for the preparation of the fragrance compounds 3 - 6.

7β-Ethynylnorlongifolane from Carbon Tetrachloride Adduct of Longifolene: Synthesis and Reactions

Dalavoy, V. S.,Deodhar, V. B.,Nayak, U. R.

, p. 5 - 7 (2007/10/02)

Sodium-t-butanol-tetrahydrofuran reagent dechlorinates 3-chloro-7β-chloroethynylnorlongifolane (3) to furnish the novel 7β-ethynylnorlongifolane (4) in 40percent yield; the olefins 5 (30percent) and 6 (7percent) are also formed.Mercuric oxide-catalyzed hydration of 4 gives 7β-acetylnorlongifolane (8) thus fixing the stereochemistry at C-7 in 4.Baeyer-Villiger oxidation/hydrolysis of 8 affords the alcohol (10a) which has been shown to be identical with the carbinol resulting from sodium-n-propanol reduction of C14-ketone (11).Hydroboration-oxidation of 4 generates an aldehyde which on silver oxide oxidation gives homoisolongifolic acid (12).

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