4751-59-1Relevant academic research and scientific papers
p-diaminobenzene derivative as potassium channel regulator, preparation method and medical applications thereof
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, (2019/12/09)
The invention relates to a p-diaminobenzene derivative as a potassium channel regulator, a preparation method and medical applications thereof, and specifically discloses a compound represented by a general formula A or a pharmaceutically acceptable salt
Visible Light Mediated Aryl Migration by Homolytic C?N Cleavage of Aryl Amines
Alpers, Dirk,Cole, Kevin P.,Stephenson, Corey R. J.
supporting information, p. 12167 - 12170 (2018/09/11)
The photocatalytic preparation of aminoalkylated heteroarenes from haloalkylamides via a 1,4-aryl migration from nitrogen to carbon, conceptually analogous to a radical Smiles rearrangement, is reported. This method enables the substitution of amino group
Regioselective synthesis of several heterocyclic fused azepines using diisobutylaluminum hydride
Cho, Hidetsura,Murakami, Kengo,Nakanishi, Hiroyuki,Isoshima, Hirotaka,Hayakawa, Kazuhide,Uchida, Itsuo
, p. 919 - 927 (2007/10/03)
5,6,7,8-Tetrahydrothieno[3,2-b]azepine,5,6,7,8-tetrahydro-1H-furo[3,2-b] azepine, and 1,4,5,6,7,8-hexahydropyrrolo[3,2-b]azepine were synthesized by the ring expansion reaction of heterocyclic fused cyclohexanone oximes with diisobutylaluminum hydride (DIBAH). The mechanism of the reaction was different from that of Beckmann rearrangement.
