475200-56-7Relevant academic research and scientific papers
Intramolecular addition of stabilized enolates to (η6-arene)ruthenium complexes: Synthesis of Ru-coordinated azaspirocycles
Pigge, F. Christopher,Fang, Shiyue,Rath, Nigam P.
, p. 1851 - 1854 (1999)
(formula presented) Stabilized enolates attached to cationic (arene)RuIICp complexes via an amide linkage were found to participate in nucleophilic aromatic addition reactions resulting in the formation of novel cyclohexadienyl-Ru azaspirocycles. Enolate addition to the activated arene ring was found to proceed with complete stereoselectivity.
