475641-94-2

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 475641-93-1 (2S,3R)-2-[(2R,4S,5R)-4-(2-Methyl-allyl)-2-phenyl-[1,3]dioxan-5-yloxy]-pent-4-ene-1,3-diol 
• 83938-00-5 ((2R,3S,6S)-3-acetoxy-6-cyano-3,6-dihydro-2H-pyran-2-yl)methyl acetate 
• 88180-36-3 2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl cyanide 
• 88180-37-4 4,6-O-Benzylidene-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl cyanide 
• 2873-29-2 D-glucal triacetate 
• 475641-64-6 (2R,4aR,6S,7R,8S,8aR)-7,8-Bis-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-6-carbaldehyde 
• 475641-81-7 Chloro-methanesulfonic acid (2R,4S,5R)-2-phenyl-5-((4R,5S)-2-phenyl-4-vinyl-[1,3,2]dioxaborinan-5-yloxy)-[1,3]dioxan-4-ylmethyl ester 
• 475641-83-9 Chloro-methanesulfonic acid (2R,4S,5R)-5-[(1S,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-but-3-enyloxy]-2-phenyl-[1,3]dioxan-4-ylmethyl ester 
• 475641-87-3 {(2R,4S,5R)-5-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-but-3-enyloxy]-2-phenyl-[1,3]dioxan-4-yl}-acetaldehyde 
• 475641-63-5 (2R,4aR,6R,7R,8S,8aR)-7,8-Bis-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-6-carbonitrile 
• 475641-71-5 [(2R,4S,5R)-2-Phenyl-5-((4R,5S)-2-phenyl-4-vinyl-[1,3,2]dioxaborinan-5-yloxy)-[1,3]dioxan-4-yl]-methanol 
• 475641-69-1 (2S,3R)-2-((2R,4S,5R)-4-Hydroxymethyl-2-phenyl-[1,3]dioxan-5-yloxy)-pent-4-ene-1,3-diol 
• 475641-66-8 (2R,4aR,6R,7S,8R,8aS)-6-((R)-1-Hydroxy-allyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 

Downstream Products

• 475641-60-2 (2R,4aR,6S,7R,9S,10aS)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-9-methyl-2-phenyl-octahydro-1,3,5-trioxa-benzocycloocten-7-ol 

Relevant academic research and scientific papers

Syntheses of the D-, E-, F-, and I-ring parts of ciguatoxin by a common strategy starting from tri-O-acetyl-D-glucal

Chiral medium-sized monocyclic ethers corresponding to the D-, E-, F-, and I-ring parts of ciguatoxin have been synthesized from tri-O-acetyl-D-glucal through a common synthetic route involving ring-closing olefin metathesis.