475977-13-0Relevant articles and documents
Metal-directed synthesis and photophysical studies of trinuclear V-shaped and pentanuclear X-shaped ruthenium and osmium metallorods and metallostars based upon 4'-(3,5-dihydroxyphenyl)-2,2':6',2"-terpyridine divergent units
Constable, Edwin C.,Handel, Robyn W.,Housecroft, Catherine E.,Morales, Angeles Farran,Ventura, Barbara,Flamigni, Lucia,Barigelletti, Francesco
, p. 4024 - 4034 (2005)
A new series of V-shaped trinuclear metallorods and X-shaped pentanuclear metallostars has been prepared by the reaction of metal complexes bearing pendant phenolic functionalities with complexes containing electrophilic ligands. Specifically, {M(tpy)sub
Fine tuning of the photoinduced energy transfer rate in trinuclear Ru/Os 2,2′:6′,2″-terpyridine complexes through structural modification of the periphery
Constable, Edwin C.,Handel, Robyn W.,Housecroft, Catherine E.,Morales, Angeles Farran,Flamigni, Lucia,Barigelletti, Francesco
, p. 1220 - 1222 (2007/10/03)
Trinuclear OsRu2 complexes were prepared and the role of peripheral thienyl units was investigated. The presence of the substituent was found to control energy transfer from ruthenium to osmium. A mononuclear complex was chosen as a spectroscop
Compositions and methods for separating heterocyclic aromatic amine bases, nucleosides, nucleotides, and nucleotide sequences
-
, (2008/06/13)
The compositions of the present invention comprise one or more palladium bound ligands that are covalently bonded to inorganic or organic solid supports. These palladium bound ligands bonded to solid supports can be used for single heterocyclic amine base separation, or can be used to separate nucleotide chain containing specific sequences from other nucleotides or nucleotide chains. In one aspect of the invention, each ligand present is individually complexed to a single Pd(II) ion. If there are from 2 to 4 ligands present in the composition, then each ligand present must be separated from the other ligands by at least 3 atoms, preferably from 3 to 20 carbon atoms or equivalent spacing.