475995-12-1

Basic information

• Product Name: (6Z,9Z,12Z,16R)-16-methoxymethoxy-20-trityloxyicosa-6,9,12-triene
• Synonyms: (6Z,9Z,12Z,16R)-16-methoxymethoxy-20-trityloxyicosa-6,9,12-triene
• CAS NO: 475995-12-1
• Molecular Weight: 594.878
• Mol File: 475995-12-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (6Z,9Z,12Z,16R)-16-methoxymethoxy-20-trityloxyicosa-6,9,12-triene(CAS DataBase Reference)
• NIST Chemistry Reference: (6Z,9Z,12Z,16R)-16-methoxymethoxy-20-trityloxyicosa-6,9,12-triene(475995-12-1)
• EPA Substance Registry System: (6Z,9Z,12Z,16R)-16-methoxymethoxy-20-trityloxyicosa-6,9,12-triene(475995-12-1)

Safety Data

• Hazardous Substances Data: 475995-12-1(Hazardous Substances Data)

Upstream product

• 475995-07-4 (R)-1-(tert-butyldiphenylsilyloxy)-3-methoxymethoxy-7-trityloxyheptane 
• 475995-06-3 (R)-1-(tert-butyldiphenylsilyloxy)-7-trityloxyheptan-3-ol 
• 475995-09-6 (R)-3-methoxymethoxy-1-(p-tolylsulfonyloxy)-7-trityloxyheptane 
• 475995-10-9 (R)-4-methoxymethoxy-8-trityloxyoctanenitrile 
• 475995-08-5 (R)-3-methoxymethoxy-7-trityloxyheptan-1-ol 
• 475995-05-2 (R)-7-(tert-butyldiphenylsilyloxy)heptane-1,5-diol 
• 475995-00-7 (R)-7-(tert-butyldiphenylsilyloxy)heptan-5-olide 
• 83606-41-1 ((3Z,6Z)-dodeca-3,6-dien-1-yl)triphenylphosphonium bromide 
• 475995-11-0 (R)-4-methoxymethoxy-8-trityloxyoctanal 

Relevant articles and documents

Synthesis of (R)-6,7-dihydro-5-HETE lactone and (S)-6,7-dihydro-5-HETE lactone by using novel yeast reduction as a key reaction

Novel yeast reduction which gave (1R,2S)-hydroxy ester 10 and (1S,5S)-lactone 11 from racemic ketoester 12 was discovered. After 10 and 11 were converted to lactone 15 and 17, enantiomeric excesses were determined as 99% and 95%, respectively. This novel