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((C6H11)2PCH2Si(CH3)2)2N(1-)*Ag(1+)=((C6H11)2PCH2Si(CH3)2)2NAg is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

476168-78-2

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476168-78-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 476168-78-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,7,6,1,6 and 8 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 476168-78:
(8*4)+(7*7)+(6*6)+(5*1)+(4*6)+(3*8)+(2*7)+(1*8)=192
192 % 10 = 2
So 476168-78-2 is a valid CAS Registry Number.

476168-78-2Downstream Products

476168-78-2Relevant academic research and scientific papers

Double silyl migration converting ORe[N(SiMe2CH2PCy2)2] to NRe[O(SiMe2CH2PCy2)2] substructures

Ozerov, Oleg V.,Gerard, Helene F.,Watson, Lori A.,Huffman, John C.,Caulton, Kenneth G.

, p. 5615 - 5625 (2002)

The reaction of (R2PCH2SiMe2)2NM (PNPRM; R = Cy; M = Li, Na, MgHal, Ag) with L2ReOX3 [L2 = (Ph3P)2 or (Ph3PO)(Me2S); X = Cl, Br] gives (PNPCy)ReOX2 as two isomers, mer,trans and mer,cis. These compounds undergo a double Si migration from N to O at 90° C to form (POPCy)ReNX2 as a mixture of mer,trans and fac,cis isomers. Additional thermolysis effects migration of CH3 from Si to Re, along with compensating migration of halide from Re to Si. DFT calculations on various structural isomers support the greater thermodynamic stability of the POP/ReN isomer vs PNP/ReO and highlight the influence of the template effect on the reactivities of these species.

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