476469-49-5

Upstream product

• 101915-63-3 3,4-bis-(tert-butyldimethylsilyl)-1,5-anhydro-2,6-dideoxy-L-lyxo-hex-1-enitol 
• 476469-46-2 (2S,3R,4S)-4-(tert-butyldimethylsiloxy)-hex-5-yn-2,3-diol 2-(para-nitrobenzoate ester) 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 62-23-7 4-nitro-benzoic acid 
• 476469-50-8 (2S,3R,4S)-3-[(2S,4S,5R,6S)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-methyl-tetrahydro-pyran-2-yloxy]-4-(tert-butyl-dimethyl-silanyloxy)-hex-5-yn-2-ol 
• 279684-66-1 (3S,4R,5S)-1-(trimethylsilyl)-4,5-epoxyhex-1-yn-3-ol 
• 476469-51-9 (2S,3R,4S)-3-[(2S,4S,5R,6S)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-methyl-tetrahydro-pyran-2-yloxy]-4-(tert-butyl-dimethyl-silanyloxy)-2-methyl-3,4-dihydro-2H-pyran 
• 279684-97-8 (2S,3R,4S)-3,4-bis-(tert-butyldimethylsiloxy)-hex-5-yn-2-ol p-nitrobenzoate ester 
• 279684-71-8 (2S,3R,4S)-3,4-bis(tert-butyldimethylsiloxy)-hex-5-yn-2-ol 

Downstream Products

• 476469-53-1 4-Nitro-benzoic acid (1S,2R,3S)-2-[(2S,4S,5R,6S)-4-acetoxy-5-((2S,4S,5R,6S)-4,5-diacetoxy-6-methyl-tetrahydro-pyran-2-yloxy)-6-methyl-tetrahydro-pyran-2-yloxy]-3-(tert-butyl-dimethyl-silanyloxy)-1-methyl-pent-4-ynyl ester 

Relevant academic research and scientific papers

Stereoselective synthesis of L-oliose trisaccharide via iterative alkynol cycloisomerization and acid-catalyzed glycosylation.

[formula: see text] The synthesis of an all-alpha L-oliose diastereomer of digitoxin provides valuable insights into the generality and protective-group dependence of acid-catalyzed glycosylations of glycals to 2-deoxycarbohydrates.