477248-72-9Relevant academic research and scientific papers
Epoxidation of bicyclo[2.2.1]hept-5-ene-2,3-endo- and exodicarboxylic acid N-arylimides
Salakhov,Bagmanova
, p. 244 - 247 (2002)
Epoxidation of endo- and exo-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid N-arylimides with a solution of peracetic acid in anhydrous dioxane affords 5,6-exo-epoxybicycloheptanedicarboxylic acid N-arylimides. The epoxidation reaction is not sensitive to
Spatial arrangement of norbornanedicarboxylic acids N-arylimides
Salakhov,Bagmanov,Nabiev
experimental part, p. 1622 - 1628 (2011/03/19)
The effect of substituents on the spatial arrangement of norbornane compounds was investigated. Norbornanedicarboxylic acids N-arylimides with OCH3, Cl, NO2 groups in the ortho-position of the aromatic ring form as conformational iso
Stereochemistry of dihydroxylation of N-arylbicyclo[2.2.1]-hept-5-ene-endo- and -exo-2,3-dicarboximides
Bagmanov
, p. 1635 - 1641 (2008/09/17)
Stereochemistry of the oxidation of N-arylbicyclo[2.2.1]hept-5-ene-endo- and-exo-2,3-dicarboximides at the double bond with peroxyacetic acid generated in situ in the presence of sulfuric acid and with an anhydrous dioxane solution of peroxyacetic acid was studied. In both cases, the reaction was stereospecific, regardless of the substituent in the N-aryl group and configuration of the imide ring, but the reaction direction depended on the presence of water in the system. In the first case, the corresponding trans-5,6-dihydroxy derivatives were formed, while in the second, exo-5,6-epoxy derivatives. The oxidation of N-arylbicyclo[2.2.1]-hept-5-ene-endo-and-exo-2,3- dicarboximides with a solution of potassium permanganate in aqueous acetone gave the corresponding N-aryl-cis-5,6-dihydroxybicyclo[2.2.1]heptane-endo-and-exo-2, 3-dicarboximides. The exo,cis,exo and exo,cis,endo configurations of the synthesized compounds were determined by 1H NMR spectroscopy.
