Cas 477334-65-9,(-)-(1R,3S,5R)-3-hydroxy-6,6-dimethylbicyclo[3.1.1]heptan-2-one

477334-65-9

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Basic information

Product Name: (-)-(1R,3S,5R)-3-hydroxy-6,6-dimethylbicyclo[3.1.1]heptan-2-one
Synonyms: (-)-(1R,3S,5R)-3-hydroxy-6,6-dimethylbicyclo[3.1.1]heptan-2-one
CAS NO:477334-65-9
Molecular Formula:
Molecular Weight: 154.209
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (-)-(1R,3S,5R)-3-hydroxy-6,6-dimethylbicyclo[3.1.1]heptan-2-one(CAS DataBase Reference)
NIST Chemistry Reference: (-)-(1R,3S,5R)-3-hydroxy-6,6-dimethylbicyclo[3.1.1]heptan-2-one(477334-65-9)
EPA Substance Registry System: (-)-(1R,3S,5R)-3-hydroxy-6,6-dimethylbicyclo[3.1.1]heptan-2-one(477334-65-9)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 477334-65-9(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 477334-65-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,7,7,3,3 and 4 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 477334-65:
(8*4)+(7*7)+(6*7)+(5*3)+(4*3)+(3*4)+(2*6)+(1*5)=179
179 % 10 = 9
So 477334-65-9 is a valid CAS Registry Number.

477334-65-9Upstream product

38651-65-9 (1R,5S)-(+)-nopinone

477334-65-9Downstream Products

477334-65-9Relevant academic research and scientific papers

A general method for the highly diastereoselective, kinetically controlled alkylation of ( )-nopinone

Campos, Kevin R,Lee, Sandra,Journet, Michel,Kowal, Jason J,Cai, Dongwei,Larsen, Robert D,Reider, Paul J

, p. 6957 - 6959 (2002)

A general method for the monoalkylation of (+)-nopinone was developed for a variety of carbon and heteroatom electrophiles to afford the kinetically controlled product 2 with high diastereoselectivity (98% d.e.) and excellent yield (75-90%).

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