477351-25-0

Basic information

• Product Name: 1-trifluoromethyl-4-[(E)-2-methyl-3,3,3-trideuterio-1-propenyl]benzene
• CAS NO: 477351-25-0
• Molecular Weight: 203.18
• Mol File: 477351-25-0.mol

Chemical Properties

• CAS DataBase Reference: 1-trifluoromethyl-4-[(E)-2-methyl-3,3,3-trideuterio-1-propenyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-trifluoromethyl-4-[(E)-2-methyl-3,3,3-trideuterio-1-propenyl]benzene(477351-25-0)
• EPA Substance Registry System: 1-trifluoromethyl-4-[(E)-2-methyl-3,3,3-trideuterio-1-propenyl]benzene(477351-25-0)

Safety Data

• Hazardous Substances Data: 477351-25-0(Hazardous Substances Data)

Upstream product

• 509095-86-7 C₁₁H₈⁽²⁾H₂ClF₃ 
• 220654-86-4 (E)-methyl 2-methyl-3-(4-(trifluoromethyl)phenyl)acrylate 
• 509095-79-8 C₁₁H₉⁽²⁾H₂F₃O 
• 455-19-6 4-Trifluoromethylbenzaldehyde 

Relevant articles and documents

Ene hydroperoxidation of isobutenylarenes within dye-exchanged zeolite Na-Y: Control of site selectivity by cation-arene interactions

The site selectivity in the singlet oxygen ene reaction of several deuterium-labeled isobutenylarenes depends on the position and the electronic nature of the aryl substitutents. For example, 1-(4-trifluoromethylphenyl)-2-methylpropene gives 82% twin sele

Control of regioselectivity by the lone substituent through steric and electronic effects in the nitrosoarene ene reaction of deuterium-labeled trisubstituted alkenes

For the ene reaction of 4-nitronitrosobenzene (ARNO) with a variety of primary and secondary lone alkyl-substituted substrates, the twix/twin regioselectivity is constant at about 85:15. In contrast, for the lone tert-butyl group and for lone aryl substituents, the twix regioisomer is obtained exclusively. These regioselectivities have been rationalized in terms of steric interactions and coordination between the enophile and the substrates in the transition states of the first reaction step.