4775-29-5Relevant academic research and scientific papers
The photodecarboxylative addition of carboxylates to phthalimides: Scope and limitations
Oelgemoeller, Michael,Cygon, Peter,Lex, Johann,Griesbeck, Axel G.
, p. 669 - 684 (2003)
Intermolecular photoinduced decarboxylative additions of a series of alkylcarboxylates to N-substituted phthalimides gave the corresponding hydroxyphthalimidines in moderate to high yields of 39-89%. The potassium salt of 1-adamantanecarboxylic acid predominately underwent simple decarboxylation when irradiated in the presence of N-methylphthalimide. In case of phthalimides carrying suitable leaving groups within the N-side chain, decarboxylation, retro-Aldol cleavage or decarbonylation preceded the intermolecular addition step.
