47756-86-5Relevant academic research and scientific papers
Activation volumes of substitution reactions on neutral and cationic organometallic platinum(IV) complexes: Definite proof of selective associative activation
Gallego, Carlos,Gonzalez, Gabriel,Martinez, Manuel,Merbach, Andre E.
, p. 2434 - 2438 (2004)
The activation volumes for the substitution reactions of a series of Pt(IV) sulfide organometallic complexes have been determined as a function of the entering and leaving ligands, as well as the inert organometallic skeleton. The results agree with the existence of a tunable associatively/dissociatively activated mechanism operating on these complexes, depending on the electronegativity of the substitution-inert spectator ligands.
