477699-15-3Relevant academic research and scientific papers
Structural isomers of aryl-substituted η3-propargyl complexes: η2-1-metalla(methylene)cyclopropene and η3-benzyl complexes
Casey, Charles P.,Boller, Timothy M.,Kraft, Stefan,Guzei, Ilia A.
, p. 13215 - 13221 (2007/10/03)
Hydride abstraction from C5Me5(CO)2Re (η2-PhC≡CCH2Ph) (1) gave a 3:1 mixture of η3-propargyl complex C5Me5(CO)2Re(η3- PhCH-C≡CPh)][BF4
Thermal isomerization of benzocyclobutene
Chapman, Orville L.,Tsou, Uh-Po Eric,Johnson, Jeffery W.
, p. 553 - 559 (2007/10/02)
Thermolysis of benzocyclobutene 13CH2, 99percent gives styrene labeled in the β (48percent), ortho (30percent), α (14percent), meta (4percent), and para (4percent) positions.The major labels (β and ortho) are consistent with a mechanism involving interconversions of the isomeric tolylmethylenes and the methylcycloheptatrienes.This mechanism also involves interconversion of o-tolylmethylene with o-xylylene and p-tolylmethylene with p-xylylene.A minor mechanism produces 25percent of styrene.This mechanism involves cleavage of the aryl carbon to the methylene carbon bond in benzocyclobutene followed by hydrogen transfer to produce styrene.Thermolysis of p-xylylene produced from paracyclophane gives styrene (55percent), p-xylene (31percent), benzocyclobutene (4percent), benzene (4percent), and toluene (3percent).Thermolysis of metacyclophane gives styrene (18percent), p-xylene (25percent), m-xylene (3percent), benzocyclobutene (1percent), benzene (7percent), and toluene (22percent).
