477945-89-4

Upstream product

• 501-53-1 benzyl chloroformate 
• 477945-88-3 8-[(2R,5S,6S)-5-(Dimethyl-phenyl-silanyl)-6-methyl-piperidin-2-yl]-octan-1-ol 
• 196491-68-6 3-[dimethyl(phenyl)silyl]glutaric anhydride 
• 477945-87-2 [(1S,2S)-13-Benzyloxy-2-(dimethyl-phenyl-silanyl)-1-methyl-5-oxo-tridecyl]-carbamic acid benzyl ester 
• 477945-84-9 (2R,3S)-5-[2-(8-Benzyloxy-octyl)-[1,3]dioxolan-2-yl]-3-(dimethyl-phenyl-silanyl)-2-methyl-pentanoic acid ethyl ester 
• 477945-83-8 (S)-5-[2-(8-Benzyloxy-octyl)-[1,3]dioxolan-2-yl]-3-(dimethyl-phenyl-silanyl)-pentanoic acid ethyl ester 
• 477945-85-0 (2R,3S)-5-[2-(8-Benzyloxy-octyl)-[1,3]dioxolan-2-yl]-3-(dimethyl-phenyl-silanyl)-2-methyl-pentanoic acid amide 
• 477945-80-5 (S)-6-((S)-4-Benzyl-2-oxo-oxazolidin-3-yl)-4-(dimethyl-phenyl-silanyl)-6-oxo-hexanoic acid benzyl ester 
• 477945-81-6 (S)-6-((S)-4-Benzyl-2-oxo-oxazolidin-3-yl)-4-(dimethyl-phenyl-silanyl)-6-oxo-hexanoic acid 
• 477945-78-1 (S)-1-((S)-4-Benzyl-2-oxo-oxazolidin-3-yl)-6-diazo-3-(dimethyl-phenyl-silanyl)-hexane-1,5-dione 
• 477945-82-7 (S)-1-((S)-4-Benzyl-2-oxo-oxazolidin-3-yl)-14-benzyloxy-3-(dimethyl-phenyl-silanyl)-tetradecane-1,6-dione 
• 477945-86-1 [(1S,2S)-4-[2-(8-Benzyloxy-octyl)-[1,3]dioxolan-2-yl]-2-(dimethyl-phenyl-silanyl)-1-methyl-butyl]-carbamic acid benzyl ester 

Downstream Products

• 477945-90-7 (2S,3S,6R)-6-(7-Carboxy-heptyl)-3-(dimethyl-phenyl-silanyl)-2-methyl-piperidine-1-carboxylic acid benzyl ester 
• 55438-00-1 8-{(2S,5S,6S)-1-[(benzyloxy)carbonyl]-5-hydroxy-6-methylpiperidinyl}octanoic acid 

Relevant academic research and scientific papers

Synthesis of enantiomerically pure all cis-2,3,6-trisubstituted piperidine: A silicon mediated total synthesis of (+)-carpamic acid

A stereoselective total synthesis of (+)-carpamic acid 1 has been achieved from the σ-symmetric 3-[dimethyl(phenyl)silyl]glutaric anhydride 11 featuring its asymmetric desymmetrisation using oxazolidinone 12. The dimethyl(phenyl)silyl group is not only ac