478072-11-6

Basic information

• Product Name: Benzoic acid, 2-[(2-methyl-2-propenyl)oxy]-, hydrazide
• CAS NO: 478072-11-6
• Molecular Formula: C11H14N2O2
• Molecular Weight: 206.244
• Mol File: 478072-11-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2-[(2-methyl-2-propenyl)oxy]-, hydrazide(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-[(2-methyl-2-propenyl)oxy]-, hydrazide(478072-11-6)
• EPA Substance Registry System: Benzoic acid, 2-[(2-methyl-2-propenyl)oxy]-, hydrazide(478072-11-6)

Safety Data

• Hazardous Substances Data: 478072-11-6(Hazardous Substances Data)

Upstream product

• 121767-60-0 2-methallyloxybenzoyl chloride 
• 119171-39-0 2-methallyloxybenzoic acid 

Downstream Products

• 478072-24-1 N'-(2-nitrobenzenesulfonyl)-2-(2-methallyloxy)benzhydrazide 

Relevant articles and documents

Acyl hydrazines as precursors to acyl radicals

The use of acyl hydrazines (hydrazides) as precursors for the stoichiometric generation of acyl radicals is explored. Two classes of substrates are examined: unsubstituted acyl hydrazines and acyl hydrazines substituted with a leaving group (2-nitrobenzenesulfonyl or 'nosyl'). Both types are successfully converted to acyl radicals, and are then trapped by nitroxide radicals to give acyloxyamine products. Cyclization reactions are demonstrated for both classes of substrates. A low temperature modification of the McFayden-Stevens reaction is also developed.