478544-24-0Relevant academic research and scientific papers
Diverse reactions of sterically protected 1,3-diphosphacyclobutane-2,4- diyls with hydride
Ito, Shigekazu,Miura, Joji,Morita, Noboru,Yoshifuji, Masaaki,Arduengo III, Anthony J.
, p. 756 - 757 (2011)
Stable 1,3-diphosphacyclobutane-2,4-diyls carrying a substituent such as benzyl moiety react with hydride to cause reductive P-C bond cleavage leading to the cyclic phosphaallyl anion, which is the synthetic intermediate of biradicals. Copyright Taylor & Francis Group, LLC.
Studies on stable 1,3-diphosphacyclobutane-2,4-diyls
Yoshifuji, Masaaki,Arduengo III, Anthony J.,Ito, Shigekazu
scheme or table, p. 335 - 339 (2009/04/06)
Various kinds of stable 1,3-diphosphacyclobutane-2,4-diyls, sterically protected by bulky Mes* (2,4,6-tri-t-butylphenyl) groups, were prepared from Mes*-phosphaethyne. The structures and physical and chemical characters were studied. They are discussed in
