478798-39-9Relevant academic research and scientific papers
Carbanion stabilization by distal silyloxy groups. Origin of the high diastereoselectivity in the formation of quaternary centers with aryllead(IV) triacetate reagents
Konopelski, Joseph P.,Lin, Jinzhen,Wenzel, Philip J.,Deng, Hongbo,Elliott, Gregory I.,Gerstenberger, Brian S.
, p. 4121 - 4123 (2007/10/03)
(formula presented) Derivatives of methyl 5-hydroxy-2-oxo-1-cyclohexanecarboxylate react with aryllead(IV) reagents in high yield and with wide variation in diastereoselectivity. Ab initio calculations are consistent with a heretofore unrecognized attract
