478798-39-9

Basic information

• Product Name: methyl 5-(tert-butyldiphenylsilyloxy)-2-oxo-cyclohexan-1-carboxylate
• Synonyms: methyl 5-(tert-butyldiphenylsilyloxy)-2-oxo-cyclohexan-1-carboxylate
• CAS NO: 478798-39-9
• Molecular Weight: 410.585
• Mol File: 478798-39-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 5-(tert-butyldiphenylsilyloxy)-2-oxo-cyclohexan-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 5-(tert-butyldiphenylsilyloxy)-2-oxo-cyclohexan-1-carboxylate(478798-39-9)
• EPA Substance Registry System: methyl 5-(tert-butyldiphenylsilyloxy)-2-oxo-cyclohexan-1-carboxylate(478798-39-9)

Safety Data

• Hazardous Substances Data: 478798-39-9(Hazardous Substances Data)

Upstream product

• 130745-59-4 4-<(tert-Butyldiphenylsilyl)oxy>cyclohexanone 
• 616-38-6 carbonic acid dimethyl ester 

Relevant articles and documents

Carbanion stabilization by distal silyloxy groups. Origin of the high diastereoselectivity in the formation of quaternary centers with aryllead(IV) triacetate reagents

(formula presented) Derivatives of methyl 5-hydroxy-2-oxo-1-cyclohexanecarboxylate react with aryllead(IV) reagents in high yield and with wide variation in diastereoselectivity. Ab initio calculations are consistent with a heretofore unrecognized attract