479544-16-6Relevant academic research and scientific papers
A stereoselective approach to functionalized cyclohexenones
Meister, Anne C.,Sauter, Paul F.,Braese, Stefan
supporting information, p. 7110 - 7116 (2013/11/06)
A catalytic enantioselective approach to 4-hydroxy-6-methylcyclohex-2- enones is presented herein. The stereogenic information is generated through a copper-catalyzed 1,4-addition to p-benzoquinone monoketal using a chiral, BINOL-based (BINOL = 1,1′-bi-2-
Enantioselective total synthesis and studies into the configurational stability of bismurrayaquinone A
Konkol, Leah C.,Guo, Fenghai,Sarjeant, Amy A.,Thomson, Regan J.
supporting information; experimental part, p. 9931 - 9934 (2011/12/04)
Lost in rotation: The concise strategy of the first enantioselective total synthesis of bismurrayaquinone A utilized traceless stereochemical exchange to form an enantioenriched biphenyl core that was elaborated in a bidirectional manner to the natural pr
Highly enantioselective catalytic conjugate additions to cyclohexadienones
Imbos, Rosalinde,Brilman, Mirjan H. G.,Pineschi, Mauro,Feringa, Ben L.
, p. 623 - 625 (2008/03/11)
(Matrix presented) Enantioselective copper phosphoramidite-catalyzed conjugate addition of dialkylzinc reagents (R2Zn) to several 4,4-disubstituted cyclohexadienones was achieved with dr's up to 99/1 and ee's up to 99%.
