479622-10-1Relevant academic research and scientific papers
Reaction of [MnII(CH2tBu)2] with bidentate diimine ligands: From simple base adducts to C-C activation of the ligand
Riollet, Virginie,Coperet, Christophe,Basset, Jean-Marie,Rousset, Laurence,Bouchu, Denis,Grosvalet, Laurent,Perrin, Monique
, p. 3025 - 3027 (2002)
Ligand transformations that depend on the substitution patterns of the diimine ligands occur upon their complexation with Mn11 dialkyl complexes. For example the 1,3-migration of the neopentyl unit from Mn to a carbon atom and the 1,2-migration of the methyl in the putative intermediate 1 give the product 2.
