479635-89-7Relevant academic research and scientific papers
Synthesis of enantiomerically enriched tertiary 2-cyclohexene-1-thiols via configurationally stable α-thio-substituted allyllithium compounds
Marr, Felix,Hoppe, Dieter
, p. 4217 - 4220 (2007/10/03)
(Equation presented) (S)-S-(2-Cyclohexenyl) N,N-diisopropylmonothiocarbamate [(-)-(S)-8] was deprotonated by sec-butyllithium/TMEDA to form a configurationally stable lithium compound (S)-9, which is the first example of a new class of α-thio-substituted
