479683-06-2

Basic information

• Product Name: 1-(4-methyl-3-cyclohexen-1-yl)-1-ethanone oxime
• Synonyms: 1-(4-methyl-3-cyclohexen-1-yl)-1-ethanone oxime
• CAS NO: 479683-06-2
• Molecular Weight: 153.224
• Mol File: 479683-06-2.mol

Chemical Properties

• CAS DataBase Reference: 1-(4-methyl-3-cyclohexen-1-yl)-1-ethanone oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-methyl-3-cyclohexen-1-yl)-1-ethanone oxime(479683-06-2)
• EPA Substance Registry System: 1-(4-methyl-3-cyclohexen-1-yl)-1-ethanone oxime(479683-06-2)

Safety Data

• Hazardous Substances Data: 479683-06-2(Hazardous Substances Data)

Upstream product

• 6090-09-1 (+-)-4-acetyl-1-methylcyclohexene 

Relevant articles and documents

X=Y-ZH Systems as potential 1,3-dipoles. Part 54: Stereo- and facially-selective formation of bridged bicyclic N-heterocycles via a sequential one-pot electrophile induced oxime→nitrone→cycloaddition sequence. Multiplication of chirality

Electrophile induced bridged-ring forming cyclisations creating azabicyclo-[3.3.1]- and azabicyclo-[3.2.1]-nitrones, followed by cycloaddition, occur stereo-, regio- and facially specifically in good to excellent yield. Chiral bridged-ring systems have been synthesised that involve multiplication of chiral centres from one to six and one to seven in one pot reactions.