479692-22-3Relevant academic research and scientific papers
Triisopropyl borate mediated N-sulfinyl imine formation
Visco, Michael D.,Reeves, Jonathan T.,Marsini, Maurice A.,Volchkov, Ivan,Busacca, Carl A.,Mattson, Anita E.,Senanayake, Chris H.
, p. 1903 - 1905 (2016)
Triisopropyl borate effects the condensation of aldehydes with sulfinamides to give N-sulfinyl imines. The reaction is amenable to 1°, 2°, and 3° alkyl aldehydes, as well as aryl, heteroaryl, and α,β-unsaturated aldehydes. In addition to tert-butanesulfin
A General Method for Imine Formation Using B(OCH2CF3)3
Reeves, Jonathan T.,Visco, Michael D.,Marsini, Maurice A.,Grinberg, Nelu,Busacca, Carl A.,Mattson, Anita E.,Senanayake, Chris H.
supporting information, p. 2442 - 2445 (2015/05/27)
Tris(2,2,2-trifluoroethyl)borate [B(OCH2CF3)3] was found to be a mild and general reagent for the formation of a variety of imines by condensation of amides or amines with carbonyl compounds. N-Sulfinyl, N-toluenesulfonyl,
Synthesis of enantiopure sulfinimines (Thiooxime S-oxides) catalyzed by Yb(OTf)3 from p-toluenesulfinamide and aldehydes in mild reaction conditions
Jiang, Zhi-Yong,Chan,Lee
, p. 1081 - 1083 (2007/10/03)
(Chemical Equation Presented) Enantiomerically pure sulfinimines as important building blocks in the asymmetric synthesis of amine derivatives are prepared in good to excellent yields from chiral p-toluene-sulfinamide with aromatic, heteroaromatic, and al
Synthesis of Sulfinimines by Direct Condensation of Sulfinamides with Aldehydes Using Cs2CO3 as an Activating and Dehydrating Reagent
Higashibayashi, Shuhei,Tohmiya, Hiraku,Mori, Tomonori,Hashimoto, Kimiko,Nakata, Masaya
, p. 457 - 460 (2007/10/03)
Chiral sulfinimines were prepared from chiral sulfinamides and aldehydes in CH2Cl2 in the presence of cesium carbonate as an amine-activating and dehydrating reagent.
