480441-20-1

Basic information

• Product Name: (4R,2''S)-4-benzyl-3[2,4-dimethylpent-4-enoyl]oxazolidin-2-one
• Synonyms: (4R,2''S)-4-benzyl-3[2,4-dimethylpent-4-enoyl]oxazolidin-2-one
• CAS NO: 480441-20-1
• Molecular Weight: 287.359
• Mol File: 480441-20-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (4R,2''S)-4-benzyl-3[2,4-dimethylpent-4-enoyl]oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,2''S)-4-benzyl-3[2,4-dimethylpent-4-enoyl]oxazolidin-2-one(480441-20-1)
• EPA Substance Registry System: (4R,2''S)-4-benzyl-3[2,4-dimethylpent-4-enoyl]oxazolidin-2-one(480441-20-1)

Safety Data

• Hazardous Substances Data: 480441-20-1(Hazardous Substances Data)

Upstream product

• 3756-30-7 1-iodo-2-methyl-2-propene 
• 101711-78-8 (3R)-3-propionyl-4-benzyloxazolidin-2-one 
• 1458-98-6 2-methyl-3-bromo-1-propene 

Downstream Products

• 75658-88-7 (+)-(2S,4R)-cis-2,4-dimethyl-δ-valerolactone 

Relevant articles and documents

A chirally catalysed ene reaction in a novel formal total synthesis of the antitumor agent laulimalide

A short highly efficient synthesis of the C3-C16 fragment 2 of laulimalide 1 is described. Fragment 2 was a key intermediate in a previous approach and thus constitutes a formal total synthesis with improved efficiency. The key steps are an Evans' alkylation, a Brown allylation and a chirally catalysed stereocontrolled ene-reaction.

Synthesis of the C(7)-C(20) fragment of spirotoamides A, B and C

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